8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ2 N,O)stannate(IV) acetonitrile monosolvate
نویسندگان
چکیده
In the title solvated salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·CH(3)CN, the Sn(IV) atom is chelated by the N,O-bidentate 8-hydroxy-quinolinate ligand and four chloride ions, generating a distorted SnONCl(4) octa-hedral coordination geometry for the metal. In the crystal, the cations are linked to the anions and the solvent mol-ecules by O-H⋯O and N-H⋯N hydrogen bonds, respectively.
منابع مشابه
8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-κ2 N,O)stannate(IV) methanol disolvate
In the reaction of 8-hy-droxy-quinoline, 2-methyl-8-hy-droxy-quinoline and stannic chloride, the 2-methyl-8-hy-droxy-quinoline is protonated, yielding the disolvated title salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·2CH(3)OH. The Sn(IV) atom in the anion is N,O-chelated by the hy-droxy-quinolinate in a cis-SnNOCl(4) octa-hedral geometry. In the crystal, the cation, anion and solvent mol-ecules ar...
متن کامل8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-κ2 N,O)stannate(IV)
The reaction of 8-hy-droxy-quinoline, 2-methyl-quinolin-8-ol and stannic chloride yields the protonated 8-hy-droxy-2-methyl-quinolinium species. In the title salt, (C(10)H(10)NO)[Sn(C(9)H(6)NO)Cl(4)], the Sn(IV) cation is N,O-chelated by the quinolin-8-olate anion and is further coordinated by four Cl(-) anions in a distorted cis-SnNOCl(4) octa-hedral geometry. In the crystal, the cation is lin...
متن کامل10-Hydroxybenzo[h]quinolinium tetrachlorido(2-methylquinolin-8-olato-κ2 N,O)stannate(IV) methanol disolvate
In the disolvated title salt, (C(13)H(10)NO)[SnCl(4)(C(10)H(8)NO)]·2CH(3)OH, the Sn(IV) atom is chelated by the N,O-bidentate 2-methyl-quinolin-8-olate ion and is further coordinated by four chloride ions, showing a distorted octa-hedral SnNOCl(4) geometry. In the crystal, the cation and anion are linked to the methanol mol-ecules by O-H⋯O and N-H⋯O hydrogen bonds.
متن کامل8-Hydroxy-2-methylquinolinium dibromido(2-methylquinolin-8-olato-κ2 N,O)zincate acetonitrile monosolvate
The reaction of 2-methyl-8-hy-droxy-quinoline and zinc bromide in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)CN, in which the Zn(II) ion is coordinated by a N,O-chelating 2-methyl-quinolin-8-olate ligand and two bromide ligands in a distorted tetra-hedral geometry. The cation is linked to the anion by an O-H⋯O hydrogen bond and the quinolinium H atom...
متن کامل8-Hydroxy-2-methylquinolinium dichlorido(2-methylquinolin-8-olato-κ2 N,O)zincate acetonitrile disolvate
The reaction of 2-methyl-8-hy-droxy-quinoline and zinc chloride in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[Zn(C(10)H(8)NO)Cl(2)]·2CH(3)CN, in which the Zn(II) atom is coordinated by an- N,O-chelating 2-methyl-quinolin-8-olate ligand and two chloride ligands in a distorted tetra-hedral geometry. The cation is linked to the heterocyclic anion by an O-H⋯O hydrogen bond and the...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010